Last updated August 22, 2011

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Safety Tutorial for CHM-107 Lab

OSHA (Occupational Safety & Health Administration) says that you have the legal right to know what chemicals you might be exposed to and what their dangers are. This is true of employees, customers, and students. For example, if you worked at a restaurant, your employer is suppose to have available to you the list of chemicals (not food) that you might come in contact with on the job and a description of their dangers. These are usually presented in material safety data sheets (MSDS for short).

Often in material safety data sheets you will find the rating given by the National Fire Protection Association. This rating was designed to be placed on diamond-shaped signs so that fire fighters would know what hazards were present when fighting a chemical fire. These signs are placed on transport vehicles, on buildings containing chemicals, and on containers of chemicals. The numbers range from 0 to 4, with 4 meaning the most hazardous. At a glance, a person can tell what the dangers are. For example, the diamond with 4,4,4 would tell you this is something extremely toxic, extremely flammable, and could explode. Fire fighters would keep their distance.

Health:
4-Deadly
3-Extreme Danger
2-Hazardous
1-Slightly Hazardous
0-Normal materials

Fire Hazard:
4-Very Flammable
3-Readily Ignitable
2-Ignited with heat
1-Combustible
0-Will not burn

Reactivity Hazard:
4-May Detonate
3-Shock & Heat may detonate
2-Violent chemical change
1-Unstable if heated
0-Stable
Specific Hazard:
OXY = Oxidizer (concentrated source of oxygen or something that behaves like oxygen)
ACID- acid
ALK – Alkali (corrosive to skin, reacts violently with acidic material)
COR- Corrosive
W – Use no water
The health and fire hazard warnings are self-explanatory. The Reactivity Hazard is mostly looking at high speed reactions which can make it explode. Other types of reactivity may be indicated in the Specific Hazard diamond.
OXY means that it can be a source of oxygen or have elements that will behave like oxygen. The chemicals don't burn themselves but speed up the burning of other chemicals. For example, potassium chlorate when heated releases oxygen atoms. When this happens, simple things like paper, plastic, wood, sugar, coins, and oil will burn white hot like a flare and could explode.
ACID means that the chemical is an acid. Strong acids can dissolve metals and release explosive hydrogen gas. It can react with other chemicals to produce a lot of heat that can start a fire. It can react with chemicals that release toxic and non-toxic gases. However, any release of gases can build up pressure and explode. Common strong acids are sulfuric acid (battery acid), hydrochloric acid (pool acid), and nitric acid.

ALK means that the chemical is alkaline which means the opposite of acid but just as dangerous. The word "alkaline" comes from a plant that grows next to salty lakes or oceans. In Arabic, it's called "Al Kali" or the saltwort plant. The ashes of this plant neutralizes acids. That is why chemicals that neutralize acids are called alkaline.

Strong alkaline chemicals are especially corrosive to skin (it turns skin into soap). Alkaline chemicals neutralize acids but in the process can put out tremendous amounts of heat that can start fires and generate gases that can build up explosive pressures. Common alkaline chemicals are ammonia (a gas used in agriculture), cleaning ammonia (ammonium hydroxide), sodium hydroxide (Drano drain opener, Easy Off oven cleaner & Red Devil soap making Lye). These chemicals can be dangerous by themselves but are more dangerous mixed with acids.

COR means that the chemical is corrosive but not because of acid or alkaline properties. It might be corrosive because of it reacts violently with water and if exposed to the moisture in skin, damages skin. Chemicals used in the computer chip industry like phosphorus trichloride, boron trichloride, aluminum trichloride, and silicon tetrachloride are in this category.

Picture is a leak from a truck carrying 12 tons of phosphorous trichloride, which has the NFPA warning of Health=4 (deadly), flammability=0 (non-flammable), reactivity=2 (violent chemical change). The Specific Hazard is listed a Water Reactive. Corrosive and irritating to living tissue. Toxic level exposure to skin causes acid-like burns. In contact with water (in tissue or with liquid water) it creates hydrochloric acid and phosphoric acid.

Some chemicals are corrosive because they react (combine) with other materials aggressively. For example, gases of the elements chlorine, fluorine, and iodine react detrimentally with human tissue and other materials. Chlorine gas is often used in public swimming pools to disinfect the water. Several emergenices have been caused by leaks of chlorine gas.

You should feel at ease because in your chemistry kit, there are no chemicals that would warrant any of these warnings.

 

 

MATERIAL SAFETY DATA SHEETS
Material Safety Data Sheet documents can be found on the Web. The MSDS sheets have a lot more information about the chemical as well. For example, the NFPA rating of 2 for health means it is hazardous, but the MSDS gives more specifics on what health hazards is involved.
Let's look at some examples of MSDS information:  
CHALK: This is in your kit and you are all familiar with the chalk at the blackboards that gets all over the room. The material safety data sheet gives rating for the NFPA diamond, which indicates that health has a rating of one, which means that it is slightly dangerous. The zero in the red means it does not burn, and the zero in the yellow means it is not reactive and is stable. One MSDS states chalk is "Irritating to the skin and eyes on contact. Inhalation will cause irritation to the lungs and mucus membrane. Irritation to the eyes will cause watering and redness. Reddening, scaling, and itching are characteristics of skin inflammation. Follow safe industrial hygiene practices and always wear protective equipment when handling this compound."

EASY OFF OVEN CLEANER: This is not in the kit but may be in your kitchen. One MSDS gives the rating of 3 for health, which is extreme danger (see diamond). It also states, "Inhalation: Not toxic by inhalation. Eye Contact: Corrosive to eyes. Skin Contact: Corrosive to skin. Signs and symptoms of overexposure include reddening of skin, tissue destruction, delayed pain. Ingestion: Not orally toxic; however, product is corrosive to mucosal membranes."

In this case, the MSDS is not exaggerating. One ingredient at 5% concentration is sodium hydroxide, which is quite corrosive, especially to the skin and eyes. The warning on the label on the can says to wear gloves, but it would also be a good idea to wear goggles as well.

A web site that has the MSDS for many household products is
http://householdproducts.nlm.nih.gov/
Be sure to visit it.

 

The chemical used as a soil substitute is called sodium polyacrylate:

As you can see from the NFPA sign the chemical is safe in all three areas: Health, flammability, and reactivity (explosiveness). One MSDS publisher does say it can be irritating to skin or eyes. (but that's about true of about any powder). This is a chemical in your kit.

 

The table below lists the chemicals in the chemistry kit and the key information from their MSDS (Material Safety Data Sheets). Become familiar with the hazards.  

 

Table of safety data for Chemicals in Chemistry Kit
built from online Material Safety Data Sheets (MSDS)
Chemical Name
Health
Flammability
Reactivity
Skin contact
Eyes
Ingestion
Inhalation
Protection
Borax, 7 grams
0=none
0=none
0=none
safe
safe
OK if less than teaspoon
mild irritant  
Sodium polyacrylate
0=none
0=none
0=none
may irritate
may irritate
Not toxic but may expand in stomach
No hazard expected  
Polyvinyl alcohol
0=none
2=moderate
0=none
safe
may irritate
Safe, no hazard expected Not expected  
Activated charcoal, 3.5 grams
1=slight
1=slight
1=slight
may irritate
may irritate
OK unless large quantities
mild irritant Goggles
Potassium iodide, 2.5 grams
1=slight
0=none
1=slight
may irritate
may irritate
Large doses may irritate GI tract. Induce vomiting
Irritation: coughing, shortness of breath Goggles
Cornstarch
0=none
1=slight
0=none
safe
may irritate
OK unless large quantities
irritation  
Sodium bicarbonate (baking soda)
0=none
0=none
1=slight
may irritate
may irritate
OK unless large quantities
irritation  
Sodium carbonate (washing soda)
1=slight
0=none
1=slight
causes irritation
causes irritation
Slightly toxic. Give 1-2 glasses of water, call physician
irritation Goggles
Ion exchange resin-sodium
0=none
1=slight
0=none
safe
may irritate
OK unless large quantities
OK unless large amount  
Ion exchange resin-Deionizing
0=none
1=slight
0=none
may irritate mildly, redness
may irritate
OK unless very large quantities
Not expected to be health hazard  
Soil test Floc-Ex tablets
1=slight
0=none
0=none
may irritate
may irritate
Harmful if swallowed, drink plenty of water, call physician
Not expected but irritant Goggles
Soil test Phosphorous tablets
1=slight
0=none
0=none
may irritate
may irritate
Do not induce vomiting, drink plenty of water, call physician
No hazard expected Goggles
Soil test Potassium tablets Sodium Tetraphenylboron <10%
1=slight
0=none
0=none
may irritate
may irritate
Harmful if swallowed, drink plenty of water, call physician
Not expected Goggles
Soil test Nitrate CTA tablets (zinc dust 1%)
1=slight
0=none
0=none
may irritate
may irritate
Harmful, induce vomitting, drink plenty of water, call physician
Not expected Goggles
Sulfur, 50 milligrams= 0.05 grams
1=slight
3=severe
0=none
may irritate
irritant, redness, pain
Considered nontoxic except in large doses
May cause coughing if large amounts Goggles
Phenolphthalein, <50 milligrams
1=slight
1=slight
0=none
my irritate irritant Once used as laxative but halted because suspected cancer hazard Not expected  
Chalk (calcium carbonate)
1=slight
0=none
0=none
may irritate
redness, itching
If large amounts swallowed, give water, get medical advice
Irritation to lungs and mucous membranes  
Biodiesel
0=none
1=slight
0=none
may irritate
may irritate
may cause gastro-intestinal irritation Not expected  
Glycerin
1=slight
1=slight
1=slight
may irritate
may irritate
irritation in large amounts Not expected  
Test strips
No MSDS given for these probably because of such small quantities and the chemicals are glued to the strips.
pH test papers
No MSDS given for these probably because of such small quantities and the chemicals are embedded in the paper
Skin Irritation
Skin irritation of these chemicals is handled by washing with soap and water. If irritation persists, seek medical advice.
Eye Irritation Eye irritation of these chemicals is handled by flushing with water for 15 minutes. If irritation persists, seek medical advice.

Other Lab Safety Practices

FIRE SAFETY:  Getting burned or setting something on fire is a major concern. 

There are two labs that will need the use of a heat source.  You will use the stove or a microwave oven.  Whenever something gets heated, there is a danger of getting burned or starting a fire.    Also, glass sometimes breaks when heated.   So be extra careful on those two labs just like being careful when cooking.

cooking cabbage

GLASSWARE SAFETY: Glass is resistant to chemicals and heat, so it's a common item in labs. But as you know, when glass breaks, it can cut you.  Your kit has several items that are made of glass including a glass thermometer, which is probably the easiest item to break.  So be extra careful with the thermometer.  

Graduated cylinders are usually made of glass, but we choose plastic ones for the kit just for extra safety.  

thermometer in beaker

CHEMICAL SAFETY:  Most chemicals in your kit are fairly safe to be around but that doesn't mean they are necessarily safe to touch, taste, or even smell.  For example, you have worked with gasoline, which is considered quite dangerous, but if you don't expose the gas to a flame, taste it, or inhale it, then you can handle it safely.  So working with chemicals in your kit is like that. They are fine if you avoid contact with them.

Gloves are included in the kit for the times your will be working with chemicals that are not good to contact.

making a test strip

EYE SAFETY:  Your eyes are the most vulnerable part of your body and the most important.   Your kit has goggles for eye protection.  The lab instructions will remind you when goggles are needed.

The goggles in your kit are made to resist liquid splashes to the eyes.  Normal glasses or other kinds of safety glasses are not good at stopping liquid from getting in the eyes.

no goggles
   

Hits from different computers since Aug, 2007

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