Study Guide for Mid-term on-campus exam and information about the Phoenix College Testing Center |
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The Testing Center is in the center of the campus in building LC (shown in yellow). It's on the second floor. You can park in the northern parking lot or the west parking lot. Their hours are 8am to 6pm Monday through Thursday and then 8am to 4pm on Friday. You should get there at least 2 hours before they close because you have a two hour time limit to do the mid-term. You shouldn't need that much time. There are some calculations on the exam. The Testing Center will supply a calculator. The Testing Center has some rules for using their center. Below is part of their instructions. Here is the link to that page. All testing requires valid state issued Photo ID or PC Student ID When you arrive at the Testing Center:
Below is more information given for online students who take tests on-campus. To see more information and the specific page, visit this page. |
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Information for Students:
It is your responsibility to read and understand the following test policies and procedures before you begin your test:
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Below is the study guide for the mid-term exam. You have a 3 week window to come into the Testing Center and take the mid-term. Dates are from April 6 to April 27.
STATES OF MATTER |
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Classical states of matter are Gas, Liquid, Solid. Some non-classical are supercooled liquid (also called glass), liquid crystal, superfluid, and plasma. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
On the exam, some of the cells above will be empty. You will fill those in. In the "Examples" column, you will only need to give one. |
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Four classifications of matter can be determined by asking 3 questions. Those four classifications are heterogeneous mixture, homogeneous mixture, element, or compound.
Using the questions in the above table, determine the classification of the following items: (Choices: heterogeneous mixture, homogeneous mixtures, element, or compound.) Root beer float, sodium chloride (table salt), aluminum foil, grape juice, toothpaste, raisin bread, quartz, syrup, Pepsi on ice, filtered orange juice, orange juice with pulp, air, pure water, muddy water, ice made from pure water, plain paper, Christmas wrapping paper, 24 karat (carat) gold ring, 14 karat gold ring, iron nail, rusty iron nail, glass in a window, urine, NaHCO3 (baking soda). (These are answered at bottom of this study guide. First see if you can figure them out). |
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More Classifications |
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Write the numbers from the list on the right under the category that best fits the statement. Hint: There are three numbers (statements) for each word.
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1) A group of two or more atoms (same or different atoms) 2) A substance that cannot be divided into simpler substances. 3) A pure substance made from 2 or more different elements chemically bonded. 4) From a Greek word meaning indivisible. 5) The plural of the word means weather. 6) Consisting of two or more parts. 7) From two words meaning a small mass. 8) A structure made from protons, neutrons, and electrons. 9) Example would be NaCl 10) Example would be "copper" 11) Example would be a spherical object with nucleus and electrons. 12) Example would be the drawing on the left. |
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Physical and Chemical Properties |
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Physical properties are properties of the substance itself. Physical properties do not mention how the element or compound reacts with another substance. That belongs to chemical properties. Some physical properties are color, form (gas/liquid/solid), odor, melting point, boiling point, malleable (easy to bend or reshape), crystalline, amorphous (no crystal structure), density, electrical conductivity (good conductor or insulator), index of refraction (how much it bends light), and more. Even without using equipment, you can identify the physical properties of substances such as color, form, taste, and odor. However, taste is not a good idea for checking most chemicals. Physical properties of a natural diamond: |
Chemical properties describe how a substance will react with other substances. For example, saying something is flammable is saying it will react with oxygen. So being flammable is a chemical property. "Strong acids dissolve metals". This is a general statement of a chemical property for strong acids. Notice that it is mentioning a different substance (metals in this case). Chemical properties tell you how a substance will react with another substance. "Sodium bicarbonate neutralizes acids." This is a chemical property statement for sodium bicarbonate. "Citric acid is incompatible with alkaline carbonates and bicarbonate." A statement that uses the word "incompatible" is stating a chemical property. In other words, it is saying that this substance will react with these other substances. It's incompatible because citric acid will no longer stay citric acid if in contact with the other substances mentioned. |
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On the test, list 6 physical properties | On the test, match the chemical property with the correct substance (Below are the correct matches. On the midterm exam, they will be scrambled. Some of the substances might be different, too.)
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PHYSICAL AND CHEMICAL CHANGES |
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A physical change is when the physical properties of a substance have changed, but the make up (formula) of the substance does not change. For example, water changing to ice is a physical change. The physical properties of ice (such as density, hardness, index of refraction) are different than those of water. However, the formula for ice (H2O) is the same as for water (H2O). So there was no chemical change only a physical change. Physical changes are usually easily reversible. |
A chemical change means the substance changes into another substance. In other words, its chemical formula changes. If a substance decomposes, that is a chemical change. If a substance reacts with another substance, that's a chemical change. For example, when the Statue of Liberty was erected in 1886, the copper metal was copper in color. However, by 1900, it had turned a turquoise color. The copper underwent a chemical change, going from metallic copper to a mixture of copper oxides, copper carbonates, copper sulfates, and copper chlorides due to exposure to various chemicals in the air and rain. Chemical changes are not as easily reversible as physical changes. That's why we worry more about unplanned chemical changes. |
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Physical Change Desired: Air Conditioning The freon in air conditioners (home or car) changes from gas to a liquid and back to a gas, which then repeats. This is a physical change because the freon does not change its chemical makeup, just its state (liquid versus gas). If freon leaks out, ultraviolet light in sunlight will decompose the freon. One decomposition product is chlorine gas. Is decomposition a chemical or physical change? |
Chemical Change Desired: Combustion for engines and stoves. Whether it is combustion in the engine of a car or on the stove, combustion requires a chemical change. In these cases, it is a hydrocarbon (compound made from carbon and hydrogen atoms) that is combining with oxygen to form carbon dioxide and water. Energy is released and we get heat to build up pressure in the engine's cylinders or heat to cook our food. A chemical change is desired in this situation because that's what will produce heat. If liquid gasoline enters the cylinder and simply turns to vapor but does not burn, is that a chemical or physical change? |
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Physical Change Desired: Lighting Most lighting depends on a physical change. The traditional light bulb has a filament that heats up and glows. That is a physical change. When the electricity is off, the filament cools down to its original physical state. However, if the bulb is cracked and air is introduced, the oxygen in the air reacts with the tungsten filament which then undergoes a chemical change as it becomes tungsten oxide, which is brittle. So the filament breaks and the light bulb stops working. In this situation, we don't want a chemical change. So the bulbs are engineered to prevent chemical changes. Candles produce light. Is that because of a physical change, chemical change or both? |
Chemical Change Not Desired: Food and Medicine Expiration dates Why do food and medicine have expiration dates? It's because there is a slow chemical process going on. After the expiration date, a significant portion of the ingredients in medicine may have undergone chemical change and converted to some other chemical. Food has the same problem. Protein, fat, sugar, starches, and vitamins that make up food will chemically break down or react with other ingredients in the food or air. Bacteria will also alter the chemical makeup. So in these situations, spoilage or degradation is occurring because of chemical changes. Preservation of food and medicine is designed to slow down or prevent chemical change. Chocolate is a food. If it melts, is that a physical change or chemical change? Does cooking of food cause a physical change or chemical change? A new bottle of Aspirin doesn't have much of a smell. However, over time it will smell like vinegar. Do you think a physical change or chemical change took place? |
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METRIC SYSTEM |
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The Metric system is based on the Earth, water, and 10 fingers. These items we all have access to, so the metric measurements can be recreated by anyone on Earth. The meter is the distance from the north pole to the equator divided by 10 million. This distance is a little longer than a yard. So we now have a distance measurement Use the body to know these metric distances |
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Use these average volumes related to the body to know metric volumes. One liter: Volume of stomach when it feels full. |
Use these average masses related to the body to know metric masses. 8 grams: Mass of eyeball |
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Regarding these questions about metric sizes that relate to the human body, the test will show the size and you will match it to the part of the body that is approximately that size. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
The easiest way to do get rid of metric prefixes is to replace the prefix with the amount that prefix represents. For example, to change 54 milliliters to liters, change the "milli" to either 0.001 or 1/1000. So that means 54 x 0.001 or do 54 x 1/1000. Both get 0.054 liters. An easy way to add a metric prefix is to divide by what the prefix represents. For example, changing 5.5 liters to milliliters means divide by 0.001 to get 5,500 milliliters. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
Convert the following metric volumes: (On the test, the amounts will be somewhat different) 3000 milliliters to liters: |
Convert the following metric distances: (On the test, the amounts will be different) 2.35 meters into centimeters: |
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Label-Factor Method (also called Dimensional Analysis) and Density problems. This approach analyzes the dimensions (unit labels) of the problem and sets up a problem so that the starting dimension is changed to the answer by using a conversion fraction that cancels out the dimensions (units) we don't want and leaves (or introduces) the ones we want in the final answer. |
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10.0 50.0 |
Here we see milliliters (mL) of gold being converted to grams (g) of gold by using the density of gold (19.3 grams per mL). The mL cancel out leaving just grams. In the second calculation, we see grams of gold being converted to milliliters of gold by using the density of gold inverted. grams is on the bottom so that they will cancel the starting grams. |
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The below tables show the same calculations setup above. It simply shows it in a spreadsheet layout. The advantage of setting up problems in a spreadsheet is that the computer will recalculate the answer whenever you change any of the values. In other words, if the 50.0 g was changed to 144.6 g, the spreadsheet would display the new mL instantly. This of course depends on the formula placed in cell G1 having the formula "=A1*D1/D2". Notice the units in red get canceled, and the units in blue remain. Note: Sometimes column "C" with the "x" is left out, but it is still understood that multiplication of the fractions is taking place. Spreadsheets also let us use the row number and column letter to identify a particular cell. For example, A1 and B1 show the starting quantity. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
The below table is the same as the above without the times "x" column.
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The below dimensional analysis setup (label-factor method) is similar to a problem in the tutorial. This setup converts 2 miles per hour into centimeters per second. Each conversion fraction have numerators and denominators that are equal to each other. These are written to cancel out the units we don't want (miles and hours) and get us to the units we do want (centimeters and seconds). Just like multiplying fractions, you multiply all of the numerators and divide by each of the denominators. You can skip any values of "1" because that doesn't change the quantity. So multiply 2 x 440 x 36 x 2.54 to get the numerator. Then divide by 0.25 followed by division by 60, then divide by the other 60. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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On the midterm exam, there will be some dimensional analysis problems that are set up that you solve. Some will be fully setup (like above) and some will be partially set up like below. Driving 424 miles in a car that gets 22.0 miles per gallon will take how many liters of gas? The dimensional analysis is set up below to solve that, but you need to write the correct dimensions (measurement units) in their proper place. B1 shows that miles is the starting units. The information of 22.0 miles per gallon is inverted so that miles is in the denominator and cancels the miles in B1. At column E we have volume in gallons, but the question wants it in liters. So columns G and H convert the gallons to liters. So you would write "miles" in E2, "liters" in H1, and "gallons" in H2. Do the arithmetic to find the quantity of liters that is written in S1. On the exam, some units will be left out for you to insert into the proper cell. |
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Ethanol is a common laboratory solvent and has a density of 0.789 g/mL. What is the mass, in grams, of 125 mL of ethanol? (Below is the partial setup to solve this problem. You will need to write the correct value and units in C1 and D1. Also, calculate F1. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Let's say you want to know the volume (in liters) of the iron in a car that gets crushed and melted down. The iron in the car weighs 3,155 lbs. Iron's density is 7.874 g/mL. The below dimensional analysis spreadsheet is setup. On the exam, some data will be left out. You should memorize how many lbs equal a kilogram. Do the arithmetic to find the quantity of liters (J2). Notice how D3 cancels B2. Notice E3 cancels the "k" in "kg" in D2. The strategy of dimensional analysis (label-factor method) is to let the units guide how you set up and solve these kind of problems. Notice that the density is inverted so that grams is on the bottom so that it cancels the "g" in "kg" in D2. "mL" is on the top because we want the answer in "Liters". On the midterm exam, you will have to decide where to place the measurements of density to get the answer. For example, the red text will not be there. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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It's a sad fact but the United States is about the last country not to convert completely to metrics. This always adds some extra conversions in chemistry. For example, in a brewery the recipe calls for a concentration of malt of 2.5 grams malt per 100mL of brew in a vat that holds 1,500 gallons of brew. How many 25-lb bags of malt is needed? (equalities: 1 gallon=3785 milliliters, 1 lb=454g) Note the dimensional analysis below. It begins with the concentration, which is mass per volume. That it multiplied by the volume of the vat. Normally, that is all that is needed to find mass because the volume cancels. However, that only works if volumes have the same units and the mass is the unit you want. Unfortunately, our units for volume don't match (mL vs. gallons). Also grams is not the weight we want. We want the weight in the number of 25-pound bags. See below dimensional analysis that shows how to solve this. On the test, you will fill in columns G and H and solve for L2 (number of bags). | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
The grams in B2 is canceled by what cell? The mL in B3 is canceled by what cell? |
TEMPERATURE SCALES |
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The top temperature is the boiling point of water. 50°C (122°F) is the hottest day on record in Phoenix, Arizona. 98.6°F (37°C) is the temperature of the body. 68°F (20°C) is considered room temperature. Most glassware for labs are calibrated to be most accurate at 20°C. 32°F (0°C) is where water coexists as liquid water and ice (freezing point). 0°F (-18°C) is temperature of a mixture of snow (or ice) and salt. Notice from freezing to boiling is 180 degrees on the Fahrenheit scale and 100 degree on the Celsius scale. That's why the fraction 180/100 or 9/5 shows up in the formulas to convert these temperatures. Also, notice the freezing point of water is 0°C but 32° on the Fahrenheit scale. So they don't both start at zero. That's why 32 degrees is subtracted from Fahrenheit temperatures before they are converted to Celsius. To go Fahrenheit to Celsius, subtract 32 first, then multiply by 5/9 to make the number of degrees fewer. That's because the scale of Celsius uses fewer degrees (steps) to go from freezing to boiling. To go from Celsius to Fahrenheit, multiply by 9/5 to get a higher number. Then add 32 because Fahrenheit is 32 degrees when Celsius is 0 degrees. On the test, this chart will be there, but you will have different degrees to convert. No formula for conversion will be given. Just use the logic given above. |
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Absolute Zero: The Kelvin scale, named after Lord Kelvin who proposed it, sets zero at absolute zero, which is the temperature where all atoms stop moving, spinning, or vibrating. Electrons & nuclei, however, continue to move. Conversion to Kelvin is fairly straightforward. Add 273.15 degrees to the Celsius temperature. It's OK to add just "273" if your Celsius degrees have no decimal places. |
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Atomic theory, Atomic mass, Molar mass |
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Using the portion of the Periodic Table on the left, answer the below questions: One mole of helium atoms weighs how many grams? |
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NOMENCLATURE |
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Write the formula for these binary & polyatomic ionic compounds. a) Potassium chloride Write the formula for these acids: Carbonic acid: |
Give the written name of these binary & polyatomic ionic compounds. a) NaCl |
At one time it was legal to spray salad bar items with a sulfite solution. This helped preserve the vegetables and fruit and kept them from turning brown. However, after a few patrons died and others were hospitalized, restaurants are banned from using sulfites or sulfur dioxide on salad bar items. What is the health problem with sulfite? |
The below image shows images of items that contain or relate to certain polyatomic ions. Many of these items were discussed in the "Nomenclature of Inorganic Compounds for Health Related Fields" tutorial and quiz. On the midterm test you will see the images. You will need to match the correct polyatomic ion with the correct image. Some images have two right answers. Either answer is fine. In the right column are the answers. You will need to memorize which polyatomic ion goes with which image. Reviewing the tutorial will help. Here's the link: Nomenclature Tutorial | |
A) Sulfite B) Nitrate or Ammonium C) Sulfate D) Acetate E) Hypochlorite F) Sulfate G) Nitrate or phosphate H) Nitrate I) Nitrate or Ammonium J) Sulfate K) Sulfite L) Perchlorate or chlorate M) Perchlorate or chlorate N) Nitrite or Nitrate O) Acetate P) Acetate Q) Acetate R) Nitrates or Chlorates S) Acetate or ammonium T) Cyanide U) Ammonium V) Cyanide W) Acetate X) Sulfite Y) Nitrate or Ammonium Z) Cyanide |
ENERGY |
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In the tutorial on energy, I said we can think of just two types of energy: Energy doing work, and energy waiting to do work. When it's doing work, we see it moving something, giving off some form of light, or changing the temperature of something like this train is doing. Work energy is also defined as a force applied to something which moves it across a distance. Like the force of lifting a brick from one height to a higher height. Or the force of a car pushing against the air as it moves down the highway. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||
Energy that is waiting to do work (has to the potential for work) is called potential energy and is recognized in 3 ways: | |||||||||||||||||||||||||||||||||||||||||||||||||||||||
1) It sits above ground level (like a lake behind a dam that sits higher than the land below the dam.) | 2) Something is compressed or stretched in someway (like compressed air or a compressed or stretched spring). | 3) Crowding of like charges or a separation of unlike charges (like a battery, capacitor, or electrons and protons on the same or different atoms. | |||||||||||||||||||||||||||||||||||||||||||||||||||||
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Kinetic energy is the energy of something that moving. However, if that moving object is not pushing anything (like a spinning flywheel, a swinging hammer, or meteor flying through space), then this energy is just waiting to do work. So this energy is similar to potential energy yet it's not normally classified as potential energy. When these moving objects start to push on something, then they do work. Again, when that object moves freely, then the kinetic energy is waiting to do work. It's like potential energy in that sense that it has the potential to do work but hasn't done it yet. Again, when the moving object pushes on something and gets it to move. Then it becomes work energy, which is a force times the distance that force is applied. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||
Chemical energy is a type of potential energy. It's similar to raising objects against gravity except instead of moving objects against the attraction of gravity, it is moving objects against the attraction of plus and minus charges. To illustrate this, let's look at the simplest of elements, hydrogen.... The hydrogen atom consists of one proton (+) and one electron (-). The proton sits in the center (nucleus) of the atom. The diagram shows the electron as a particle orbiting the nucleus. If an electron is moved farther away from the proton, it takes energy because they are attracted to each other (like gravity). The farther away the electron has been moved away from the proton, the more energy it takes, and the more potential energy stored in the electron. When the electron drops back closer to the proton, it will convert that potential energy to light energy. The light energy can be in the form of infrared, visible, ultraviolet, or even X-ray light. Helium has two protons. Would you think it takes more or less energy to pull an electron away from the helium nucleus compared to a hydrogen nucleus? Would an electron that has been pulled away from a helium nucleus have more or less potential energy than an electron that was pulled away from an hydrogen nucleus? |
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Horsepower is work energy per minute. It came from the fact that one horse using a pulley could lift 330 lbs 100 feet in one minute. So that's 330lbs x 100 ft / 1 min. Or 33,000 ft·lbs/min. In other words, the pounds (lbs) times the feet divided by the minutes will come out to 33000 if one horsepower. We need an elevator to lift 1550 lbs. If this elevator gets 1550 lbs up to the 20th floor (200. feet) within half a minute, what horsepower motor is it using? Dimensional analysis uses the trick of letting the dimensions guide how to do the problem. Since horsepower has the units of ft·lbs/min, then it says to multiply the feet by the pounds, then divide by the minutes. On the exam, the values will be different and the problem won't be totally set up.
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